Solvent-free chemoselective oxidation of thioethers and thiophenes by mechanical milling.
نویسندگان
چکیده
Organosulphur compounds can be easily and selectively oxidized to sulfones using a small excess of Oxone(®) (1.6 eq.) under solventless mechanical milling conditions. This green procedure has been efficiently applied to a series of model compounds and to the desulphurization of medium/high sulphur content paraffins (up to 3000 mg kg(-1)).
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 95 شماره
صفحات -
تاریخ انتشار 2012